PES for filtration applications

The engineering thermoplastic polyethersulfone (PES) is becoming the material of choice to produce hollow fibers for fluid transport and cast membranes for filtration applications due to its high mechanical, chemical, and thermal properties and a microporous structure that makes PES a very-effective filter medium. 

 

Sumitomo Chemical Advanced Technologies offers four PES grades (4800P, 5200P, 5400P, and 5900P) for the filtration market segment under the tradename SumikaExcel™. Each grade is supplied as a powder, which is subsequently dissolved in an organic solvent and either spun into hollow fibers or cast as membranes with very controllable pore size/diameter and distribution, excellent strength and chemical stability, and high porosity and permeability for long use-life, low fouling, and superior separation performance. Such filter media are used in applications as diverse as hollow-fiber dialyzer filter packs for low- and high-flux hemodialysis procedures, particle filtration for wastewater treatment, microfiltration for beverage clarification, ultrafiltration drinking-water decontamination, reverse osmosis for seawater desalination or drinking-water purification, and chemical separators. 

 

PES is an amber-transparent, amorphous engineering thermoplastic known for its high mechanical properties, including high strength and impact resistance, low creep even at elevated temperatures and loads, low warpage (owing to the complete absence of crystallization), high dimensional stability, and low coefficient of linear thermal expansion (CLTE) over a broad temperature range.  The polymer also provides superior stress-crack and good and broad chemical resistance (particularly for an amorphous thermoplastic). It also offers excellent thermal stability, including long-term heat aging and performance at elevated temperatures. Filtration applications are enhanced by the microporous structure that can be created in either hollow tubes or cast membranes. (Although not critical in this market, PES also has inherent flame retardance[4], low smoke, and minimal outgasing.) Combined, these attributes enable PES hollow fibers and cast membranes to withstand high-pressure cleaning processes like gas backwashing, as well as super-heated steam, e-beam radiation and ethylene-oxide sterilization, and exposure to sodium hydroxide, sodium hypochlorite, and surfactants. That, in turn, helps ensure high flow, long use-life, and low fouling in critical filtration media.

 

 

Sumitomo Chemical is unique in the plastics industry as the world’s sole PES manufacturer that maintains dedicated PES polymerization facilities (in Chiba and Ehime, Japan). This eliminates the possibility of cross-contamination with other polymers and also simplifies the supply chain for processors and OEMs.

 

PES polymer is offered pelletized for injection molding, extrusion, and film processes and in powder form for cast films, filtration membranes, and as an epoxy additive for composites, high-temperature paints and coatings, and adhesives. PES grades are used in the aerospace, automotive, electrical/electronics, medical-device, and food-handling industries.

 

Sumitomo Chemical Advanced Technologies LLC, formerly called Sumika Electronic Materials and a wholly owned subsidiary of Sumitomo Chemical Co., Ltd., is a leading manufacturer of polyethersulfone (PES), liquid crystal polymer (LCP), and high-performance alloy resins.