Silky Very Water-Resistant Spray Sunscreen

AkzoNobel
T: 888-331-6212
F: 908-707-3664
E: personalcare.usa@akzonobel.com
W: www.akzonobel.com/PersonalCare

Phase A
Deionized water 57.26
Hydramol PGPD Ester (Lubrizol Advanced Materials)
(PEG/PPG-8/3 diisostearate) 2.50
1,3-Butanediol (Alfa Aesar) (Butylene glycol) 2.00
D-Panthenol USP (BASF) (Panthenol) 0.25
Allantoin (Jeen International) 0.20
Dissolvine NA2-S chelate (AkzoNobel Functional
Chemicals) (Disodium EDTA) 0.05

Phase B
Wickenol 150 (Alzo Inc) (Isostearyl neopentanoate) 5.00
Neo Heliopan 303 (Symrise) (Octocrylene) 2.00
Neo Heliopan HMS (Symrise) (Homosalate) 12.00
Neo Heliopan 357 (Symrise) (Avobenzone) 3.00
Neo Heliopan OS (Symrise) (Ethylhexyl salicylate) 5.00
Neo Heliopan BB (Symrise) (Benzophenone-3) 4.00
Phenonip (Clariant) (Phenoxyethanol (and) methylparaben
(and) ethylparaben (and) butylparaben (and) propylparaben
(and) isobutylparaben) 1.00

Phase C
Pemulen TR-2 (Lubrizol Adv. Materials)
(Acrylates/C10-30 alkyl acrylate crosspolymer) 0.15

Phase D
Triethanolamine-99% (Dow Chemical) (Triethanolamine) 0.19
Deionized water 1.00

Phase E
Dermacryl E (45% active) polymer (AkzoNobel Personal Care) (Styrene/acrylates copolymer) 4.40

Phase F
50% Citric Acid Solution (Citric acid (and) water) 0.00

Procedure
In the main kettle, add and mix phase A until uniform. In a side kettle, add and mix phase B. Heat to 45-50°C until the solid sunscreen is fully incorporated. Cool to room temperature. Sprinkle in Pemulen TR-2 into phase B under the homogenizer. Mix until the polymer is dispersed and homogeneous in the oil. Put phase A under the homogenizer and slowly add phase B into Phase A with moderate speed under the homogenizer (2,500 rpm for 20 minutes). Neutralize the batch with triethanolamine-99% and mix until uniform. Add phase E and mix until uniform. Adjust the pH to 6.5 -7.0 with phase F. Drop the batch.

Properties
Color—White; Appearance—Opaque; pH—6.3-7.0; Viscosity—1200-3000 cps LVDV #63, 30 rpm, 25°C; Packaging—Pump spray bottle.